The option to create a whitelist is only being offered on systems that are not older than 30 days.
If your system has been installed more than 30 days ago, the Whitelist Creator can not be started via the Start Center. If you still want to create a whitelist you can use the ‘SDPrepPos’ in the Spybot – Search & Destroy program folder, by default:
Windows XP: C:\Program Files\Spybot – Search & Destroy 2
Windows Vista or Windows 7 or Windows 8: C:\Programs (x86)\Spybot – Search & Destroy 2
A Whitelist should only be created on a system that is known to be uninfected.
We recommend that you only use it on a new system, after all software has been set up,
but before connecting it to the Internet.